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Issue 69, 2012
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Ligand effects on the stereochemistry of Stille couplings, as manifested in reactions of Z-alkenyl halides

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Abstract

Unexpected losses in stereochemistry from Stille reactions involving Z-alkenyl halides have been shown to be ligand dependent. A new set of reaction conditions has been developed that, in most cases, leads to highly stereoselective cross-couplings under mild conditions, along with improved yields.

Graphical abstract: Ligand effects on the stereochemistry of Stille couplings, as manifested in reactions of Z-alkenyl halides

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Publication details

The article was received on 08 May 2012, accepted on 04 Jul 2012 and first published on 23 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC33294A
Citation: Chem. Commun., 2012,48, 8661-8663
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    Ligand effects on the stereochemistry of Stille couplings, as manifested in reactions of Z-alkenyl halides

    G. Lu, K. R. Voigtritter, C. Cai and B. H. Lipshutz, Chem. Commun., 2012, 48, 8661
    DOI: 10.1039/C2CC33294A

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