Issue 53, 2012

Unique catalysis of gold nanoparticles in the chemoselective hydrogenolysis with H2: cooperative effect between small gold nanoparticles and a basic support

Abstract

Gold nanoparticles on hydrotalcite act as a heterogeneous catalyst for the chemoselective hydrogenolysis of various allylic carbonates to the corresponding terminal alkenes using H2 as a clean reductant. The combination of gold nanoparticles and basic supports elicited significantly unique and selective catalysis in the hydrogenolysis.

Graphical abstract: Unique catalysis of gold nanoparticles in the chemoselective hydrogenolysis with H2: cooperative effect between small gold nanoparticles and a basic support

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr 2012
Accepted
09 May 2012
First published
10 May 2012

Chem. Commun., 2012,48, 6723-6725

Unique catalysis of gold nanoparticles in the chemoselective hydrogenolysis with H2: cooperative effect between small gold nanoparticles and a basic support

A. Noujima, T. Mitsudome, T. Mizugaki, K. Jitsukawa and K. Kaneda, Chem. Commun., 2012, 48, 6723 DOI: 10.1039/C2CC32850J

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