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Issue 62, 2012
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Highly stereoselective Ru(II)–Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate

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Abstract

The Ru(II)–Pheox complex is an efficient catalyst for the intermolecular cyclopropanation of various terminal olefins with succinimidyl diazoacetate. This catalytic system can perform under mild conditions, and the desired cyclopropane products are obtained in high yields with excellent diastereoselectivity and enantioselectivity.

Graphical abstract: Highly stereoselective Ru(ii)–Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate

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Publication details

The article was received on 17 Apr 2012, accepted on 08 Jun 2012 and first published on 12 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC32706F
Citation: Chem. Commun., 2012,48, 7750-7752
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    Highly stereoselective Ru(II)–Pheox catalyzed asymmetric cyclopropanation of terminal olefins with succinimidyl diazoacetate

    S. Chanthamath, K. Phomkeona, K. Shibatomi and S. Iwasa, Chem. Commun., 2012, 48, 7750
    DOI: 10.1039/C2CC32706F

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