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Issue 52, 2012
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Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

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Abstract

An efficient aerobic reduction of olefins, internal as well as terminal, is developed using guanidine as an organocatalyst. A remarkable chemoselectivity in reduction has been demonstrated in the presence of a variety of functional groups and protective groups and a selective reduction of a terminal olefin in the presence of an internal olefin is revealed.

Graphical abstract: Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

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Publication details

The article was received on 12 Apr 2012, accepted on 08 May 2012 and first published on 09 May 2012


Article type: Communication
DOI: 10.1039/C2CC32611F
Citation: Chem. Commun., 2012,48, 6583-6585
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    Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

    M. Lamani, R. S. Guralamata and K. R. Prabhu, Chem. Commun., 2012, 48, 6583
    DOI: 10.1039/C2CC32611F

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