Issue 48, 2012

Hypercohin A, a new polycyclic polyprenylated acylphloroglucinol possessing an unusual bicyclo[5.3.1]hendecane core from Hypericum cohaerens

Abstract

Hypercohin A (1), an unprecedented polycyclic polyprenylated acylphloroglucinol featuring with an unusual bicyclo[5.3.1]hendecane core, was isolated from Hypericum cohaerens. Its structure and absolute configurations were elucidated by extensive NMR methods and crystal X-ray diffractions of its p-bromobenzoate ester (2).

Graphical abstract: Hypercohin A, a new polycyclic polyprenylated acylphloroglucinol possessing an unusual bicyclo[5.3.1]hendecane core from Hypericum cohaerens

Supplementary files

Article information

Article type
Communication
Submitted
01 Apr 2012
Accepted
18 Apr 2012
First published
19 Apr 2012

Chem. Commun., 2012,48, 5998-6000

Hypercohin A, a new polycyclic polyprenylated acylphloroglucinol possessing an unusual bicyclo[5.3.1]hendecane core from Hypericum cohaerens

X. Yang, X. Deng, X. Liu, C. Wu, X. Li, B. Wu, H. Luo, Y. Li, H. Xu, Q. Zhao and G. Xu, Chem. Commun., 2012, 48, 5998 DOI: 10.1039/C2CC32352D

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