Issue 40, 2012
From the journal:

Chemical Communications

Palladium-catalyzed monoselective C–H borylation of acetanilides under acidic conditions†

Bin Xiao,‡a   Yi-Ming Li,‡a   Zhao-Jing Liu,a   Han-Yi Yanga  and  Yao Fu*a  

* Corresponding authors

a Department of Chemistry, Joint Laboratory of Green Synthetic Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China

Abstract

A practical Pd-catalyzed reaction was developed to achieve C–H activation/C–B cross-coupling of acetanilides under acidic conditions. The new reaction shows a good functional group tolerance and an exclusive mono-selectivity. This C–H borylation method may provide a generally applicable route for the conversion of C–H moieties into many other types of bonds.

Graphical abstract: Palladium-catalyzed monoselective C–H borylation of acetanilides under acidic conditions

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Article information

DOI
https://doi.org/10.1039/C2CC31737K
Article type
Communication
Submitted
08 Mar 2012
Accepted
24 Mar 2012
First published
12 Apr 2012

Chem. Commun., 2012,48, 4854-4856

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Palladium-catalyzed monoselective C–H borylation of acetanilides under acidic conditions

B. Xiao, Y. Li, Z. Liu, H. Yang and Y. Fu, Chem. Commun., 2012, 48, 4854 DOI: 10.1039/C2CC31737K

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