Issue 41, 2012
From the journal:

Chemical Communications

Pentavalent uranium trans-dihalides and -pseudohalides†

Andrew J. Lewis,a   Eiko Nakamaru-Ogiso,b   James M. Kikkawa,c   Patrick J. Carrolla  and  Eric J. Schelter*a  

* Corresponding authors

a P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Pennsylvania 19104, Philadelphia, USA
E-mail: schelter@sas.upenn.edu

b Department of Biochemistry and Biophysics, Perelman School of Medicine, University of Pennsylvania, Pennsylvania 19104, Philadelphia, USA

c Department of Physics & Astronomy, University of Pennsylvania, Philadelphia, USA

Abstract

Pentavalent uranium complexes of the formula UVX2[N(SiMe3)2]3 (X = F−, Cl−, Br−, N3−, NCS−) are accessible from the oxidation of UIII[N(SiMe3)2]3 through two sequential, one-electron oxidation reactions (halides) and substitution through salt metathesis (pseudohalides). Uranium(V) mixed-halides are also synthesized by successive one-electron oxidation reactions.

Graphical abstract: Pentavalent uranium trans-dihalides and -pseudohalides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC31601C
Article type
Communication
Submitted
02 Mar 2012
Accepted
24 Mar 2012
First published
26 Mar 2012

Chem. Commun., 2012,48, 4977-4979

Permissions

Request permissions

Pentavalent uranium trans-dihalides and -pseudohalides

A. J. Lewis, E. Nakamaru-Ogiso, J. M. Kikkawa, P. J. Carroll and E. J. Schelter, Chem. Commun., 2012, 48, 4977 DOI: 10.1039/C2CC31601C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements