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Issue 55, 2012
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An elegant access to formation and vaporization enthalpies of ionic liquids by indirect DSC experiment and “in silico” calculations

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Abstract

We used DSC for determination of the reaction enthalpy of the synthesis of the ionic liquid [C4mim][Cl]. A combination of DSC and quantum chemical calculations presents a new, indirect way to study thermodynamics of ionic liquids. The new procedure was validated with two direct experimental measurements and MD simulations.

Graphical abstract: An elegant access to formation and vaporization enthalpies of ionic liquids by indirect DSC experiment and “in silico” calculations

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Publication details

The article was received on 28 Feb 2012, accepted on 15 May 2012 and first published on 16 May 2012


Article type: Communication
DOI: 10.1039/C2CC31504A
Citation: Chem. Commun., 2012,48, 6915-6917
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    An elegant access to formation and vaporization enthalpies of ionic liquids by indirect DSC experiment and “in silico” calculations

    S. P. Verevkin, D. H. Zaitsau, V. N. Emel'yanenko, C. Schick, S. Jayaraman and E. J. Maginn, Chem. Commun., 2012, 48, 6915
    DOI: 10.1039/C2CC31504A

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