Issue 33, 2012
From the journal:

Chemical Communications

Design of main-chain polymers of chiral imidazolidinone for asymmetric organocatalysis application†‡

Naoki Haraguchi,*a   Hitomi Kiyono,a   Yu Takemuraa  and  Shinichi Itsunoa  

* Corresponding authors

a 1-1 Hibarigaoka, Tenpaku-Cho, Japan
E-mail: haraguchi@ens.tut.ac.jp
Fax: +81 532 43 5833
Tel: +81 532 44 6812

Abstract

Main-chain polymers of chiral imidazolidinone were successfully synthesized by reaction of chiral imidazolidinone dimers with disulfonic acid. Chiral imidazolidinones were incorporated into the main-chain of the polymer by ionic bonding. These polymers could be used as polymeric chiral organocatalysts for asymmetric Diels–Alder reactions.

Graphical abstract: Design of main-chain polymers of chiral imidazolidinone for asymmetric organocatalysis application

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC18115K
Article type
Communication
Submitted
28 Dec 2011
Accepted
02 Mar 2012
First published
02 Mar 2012

Chem. Commun., 2012,48, 4011-4013

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Design of main-chain polymers of chiral imidazolidinone for asymmetric organocatalysis application

N. Haraguchi, H. Kiyono, Y. Takemura and S. Itsuno, Chem. Commun., 2012, 48, 4011 DOI: 10.1039/C2CC18115K

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