Issue 29, 2012
From the journal:

Chemical Communications

Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets†

Jesús Ferrando-Soria,a   Thais Grancha,a   Miguel Julve,a   Joan Cano,a   Francesc Lloret,*a   Yves Journaux,*b   Jorge Pasán,c   Catalina Ruiz-Pérezc  and  Emilio Pardo*a  

* Corresponding authors

a Depto. de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, València, Spain
E-mail: Emilio.Pardo@upmc.fr
Fax: +34 963543273
Tel: +34 963544440

b Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris 6, F-75252 Paris, France
E-mail: Yves.Journaux@upmc.fr
Fax: +33 144273841
Tel: +33 144275562

c Laboratorio de Rayos X y Materiales Moleculares, Depto. de Fisica Fundamental II, Universidad de La Laguna, 38201 Tenerife, Spain

Abstract

Increasing dimensionality [from 2D (1) to 3D (2)] and TC [from 10 (1) to 20 K (2)] in two new oxamato-bridged heterobimetallic MnII2CuII3 open-frameworks result from the steric hindrance provided by the different alkyl substituents of the N-phenyloxamate bridging ligands.

Graphical abstract: Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

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Article information

DOI
https://doi.org/10.1039/C2CC17767F
Article type
Communication
Submitted
12 Dec 2011
Accepted
14 Feb 2012
First published
15 Feb 2012

Chem. Commun., 2012,48, 3539-3541

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Ligand effects on the dimensionality of oxamato-bridged mixed-metal open-framework magnets

J. Ferrando-Soria, T. Grancha, M. Julve, J. Cano, F. Lloret, Y. Journaux, J. Pasán, C. Ruiz-Pérez and E. Pardo, Chem. Commun., 2012, 48, 3539 DOI: 10.1039/C2CC17767F

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