Issue 29, 2012
From the journal:

Chemical Communications

Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols†

Wuming Yan,a   Xiaohan Ye,a   Keith Weise,a   Jeffrey L. Petersena  and  Xiaodong Shi*a  

* Corresponding authors

a C. Eugene Bennett Department of Chemistry, West Virginia University, Morgantown, USA
E-mail: Xiaodong.Shi@mail.wvu.edu
Fax: +1-304-293-4904
Tel: +1-304-293-3435 x6438

Abstract

Allene triazole derivatives were successfully synthesized for the first time through iron catalyzed regioselective triazole addition to tertiary propargyl alcohols. The reaction proceeds under mild conditions, giving the desired allene-triazoles in good to excellent yields (up to 96%). The resulting allene-triazoles were confirmed by X-ray crystallography and indicated improved stability.

Graphical abstract: Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols

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Article information

DOI
https://doi.org/10.1039/C2CC17522C
Article type
Communication
Submitted
01 Dec 2011
Accepted
15 Feb 2012
First published
15 Feb 2012

Chem. Commun., 2012,48, 3521-3523

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Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols

W. Yan, X. Ye, K. Weise, J. L. Petersen and X. Shi, Chem. Commun., 2012, 48, 3521 DOI: 10.1039/C2CC17522C

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