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Issue 29, 2012
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Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols

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Abstract

Allene triazole derivatives were successfully synthesized for the first time through iron catalyzed regioselective triazole addition to tertiary propargyl alcohols. The reaction proceeds under mild conditions, giving the desired allene-triazoles in good to excellent yields (up to 96%). The resulting allene-triazoles were confirmed by X-ray crystallography and indicated improved stability.

Graphical abstract: Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols

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Publication details

The article was received on 01 Dec 2011, accepted on 15 Feb 2012 and first published on 15 Feb 2012


Article type: Communication
DOI: 10.1039/C2CC17522C
Citation: Chem. Commun., 2012,48, 3521-3523
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    Synthesis of allene triazole through iron catalyzed regioselective addition to propargyl alcohols

    W. Yan, X. Ye, K. Weise, J. L. Petersen and X. Shi, Chem. Commun., 2012, 48, 3521
    DOI: 10.1039/C2CC17522C

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