In situ synthesis of Cu–BTC (HKUST-1) in macro-/mesoporous silica monoliths for continuous flow catalysis

Alexander Sachse; Rob Ameloot; Bernard Coq; François Fajula; Benoît Coasne; Dirk De Vos; Anne Galarneau

doi:10.1039/C2CC17190B

In situ synthesis of Cu–BTC (HKUST-1) in macro-/mesoporous silica monoliths for continuous flow catalysis

Alexander Sachse,^a Rob Ameloot,^b Bernard Coq,^a François Fajula,^a Benoît Coasne,^a Dirk De Vos^b and Anne Galarneau*^a

Author affiliations

* Corresponding authors

^a Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM2-ENSCM-UM1, ENSCM, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France
E-mail: anne.galarneau@enscm.fr

^b Center for Surface Chemistry and Catalysis, Katholieke Universiteit Leuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium
E-mail: Dirk.DeVos@biw.kuleuven.be

Abstract

The metal–organic framework Cu–BTC has been successfully synthesized as nanoparticles inside the mesopores of silica monoliths featuring a homogeneous macropore network enabling the use of Cu–BTC for continuous flow applications in liquid phase with low pressure drop. High productivity was reached with this catalyst for the Friedländer reaction.

Supplementary files

Publication details

The article was received on 18 Nov 2011, accepted on 20 Mar 2012 and first published on 20 Mar 2012

Article type: Communication

DOI: 10.1039/C2CC17190B

Citation: Chem. Commun., 2012,48, 4749-4751

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In situ synthesis of Cu–BTC (HKUST-1) in macro-/mesoporous silica monoliths for continuous flow catalysis

A. Sachse, R. Ameloot, B. Coq, F. Fajula, B. Coasne, D. De Vos and A. Galarneau, Chem. Commun., 2012, 48, 4749
DOI: 10.1039/C2CC17190B
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Chemical Communications

In situ synthesis of Cu–BTC (HKUST-1) in macro-/mesoporous silica monoliths for continuous flow catalysis

Abstract

Supplementary files

Publication details

In situ synthesis of Cu–BTC (HKUST-1) in macro-/mesoporous silica monoliths for continuous flow catalysis

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