Issue 20, 2012
From the journal:

Chemical Communications

Copper complexes of a novel non-innocent quadridentate ligand†‡

Gojko Buncic,a   Zhiguang Xiao,a   Simon C. Drew,a   Jonathan M. White,a   Anthony G. Wedda  and  Paul S. Donnelly*a  

* Corresponding authors

a School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, University of Melbourne, Parkville, Australia
E-mail: pauld@unimelb.edu.au
Fax: +61 3 9347 5180

Abstract

Quadridentate ligand H2L binds Cu(I) to form salt [CuI(H2L)]BF4 which undergoes aerial oxidation in solution with isolation of the diamagnetic salt [CuIIL˙−]BF4 where π-radical anion L˙− is the (1e−, 2H+) oxidation product of H2L.

Graphical abstract: Copper complexes of a novel non-innocent quadridentate ligand

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Article information

DOI
https://doi.org/10.1039/C2CC16658E
Article type
Communication
Submitted
26 Oct 2011
Accepted
02 Dec 2011
First published
02 Dec 2011

Chem. Commun., 2012,48, 2570-2572

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Copper complexes of a novel non-innocent quadridentate ligand

G. Buncic, Z. Xiao, S. C. Drew, J. M. White, A. G. Wedd and P. S. Donnelly, Chem. Commun., 2012, 48, 2570 DOI: 10.1039/C2CC16658E

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