Issue 3, 2012
From the journal:

Chemical Communications

Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes†

Michael Danz,a   Ralf Tonner*a  and  Gerhard Hilt*a  

* Corresponding authors

a Fachbereich Chemie, Hans-Meerwein-Str., 35043 Marburg, Germany
E-mail: Hilt@chemie.uni-marburg.de, Tonner@chemie.uni-marburg.de
Fax: +49 6421 2825677
Tel: +49 6421 2825601

Abstract

A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity.

Graphical abstract: Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

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Article information

DOI
https://doi.org/10.1039/C1CC15980A
Article type
Communication
Submitted
26 Sep 2011
Accepted
01 Nov 2011
First published
14 Nov 2011

Chem. Commun., 2012,48, 377-379

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Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

M. Danz, R. Tonner and G. Hilt, Chem. Commun., 2012, 48, 377 DOI: 10.1039/C1CC15980A

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