Issue 2, 2012
From the journal:

Chemical Communications

Columnar self-assembly of rhomboid macrocyclic molecules via step-like intermolecular interaction. Crystal formation and gelation†

Tomohito Ide,a   Daisuke Takeuchia  and  Kohtaro Osakada*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, 4359 Nagatsuda, Midori-ku, Yokohama 226-8503, Japan
E-mail: kosakada@res.titech.ac.jp
Fax: +81 45-924-5224
Tel: +81 45-924-5224

Abstract

Two macrocyclic compounds with a rhomboid molecular shape, composed of a π-conjugated framework and an imine or amine functionality, were synthesized. The amine-containing macrocycle crystallizes with step-like interaction of each molecule, forming a columnar arrangement, although dispersion of the imine gelates upon ultrasonification.

Graphical abstract: Columnar self-assembly of rhomboid macrocyclic molecules via step-like intermolecular interaction. Crystal formation and gelation

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Article information

DOI
https://doi.org/10.1039/C1CC15311K
Article type
Communication
Submitted
26 Aug 2011
Accepted
03 Nov 2011
First published
21 Nov 2011

Chem. Commun., 2012,48, 278-280

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Columnar self-assembly of rhomboid macrocyclic molecules via step-like intermolecular interaction. Crystal formation and gelation

T. Ide, D. Takeuchi and K. Osakada, Chem. Commun., 2012, 48, 278 DOI: 10.1039/C1CC15311K

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