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Issue 41, 2012
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Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

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Abstract

Novel cyclometallated iridium–Pt/Pd dinuclear complexes containing the bridging ligand 2,2′:5′,2′′-terpyridine (BPP) and the peripheral phenylpyridine (ppy) ligand produced hydrogen under both visible (470 nm) and UV (350 nm) irradiation. The turnover numbers using visible light were found to be significantly higher, indicating an interplay between two independent excited states, only one of which produces H2 efficiently.

Graphical abstract: Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

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Publication details

The article was received on 29 Aug 2012, accepted on 04 Sep 2012 and first published on 06 Sep 2012


Article type: Communication
DOI: 10.1039/C2DT32028B
Citation: Dalton Trans., 2012,41, 12678-12680
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    Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

    S. Soman, G. Singh Bindra, A. Paul, R. Groarke, J. C. Manton, F. M. Connaughton, M. Schulz, D. Dini, C. Long, M. T. Pryce and J. G. Vos, Dalton Trans., 2012, 41, 12678
    DOI: 10.1039/C2DT32028B

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