Issue 4, 2013

A novel sandwich-type tungstoarsenate containing a cagelike {Ca6} cluster with a water molecule enwrapped

Abstract

A cage-like {[Ca(H2O)]6(H2O)}12+ cluster with a water molecule enwrapped, sandwiched by two novel [As4W6O34]12− fragments, has been obtained, and the extension of these clusters from molecules into a 2-D layer occurs through [Ca(H2O)5]2+ linkers, which represents the first heteropolyoxoanion (HPA) constituted by [As4W6O34]12− and the unprecedented high nuclearity {[Ca(H2O)]6(H2O)}12+ cluster.

Graphical abstract: A novel sandwich-type tungstoarsenate containing a cagelike {Ca6} cluster with a water molecule enwrapped

Supplementary files

Article information

Article type
Communication
Submitted
06 Sep 2012
Accepted
08 Nov 2012
First published
12 Nov 2012

Dalton Trans., 2013,42, 874-878

A novel sandwich-type tungstoarsenate containing a cagelike {Ca6} cluster with a water molecule enwrapped

X. Ma, P. Ma, D. Zhang, J. Hua, C. Zhang, T. Huang, J. Wang and J. Niu, Dalton Trans., 2013, 42, 874 DOI: 10.1039/C2DT32061D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements