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Issue 26, 2012
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Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen

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Abstract

A new {Fe(NO)2}10 dinitrosyl iron complex possessing a 2,9-dimethyl-1,10-phenanthroline ligand has been prepared. This complex exhibits dioxygenase activity, converting NO to nitrate (NO3) anions. During the oxygenation reaction, formation of reactive nitrating species is implicated, as shown in the effective o-nitration with a phenolic substrate.

Graphical abstract: Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

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Publication details

The article was received on 23 Feb 2012, accepted on 03 Apr 2012 and first published on 11 Apr 2012


Article type: Communication
DOI: 10.1039/C2DT30443K
Citation: Dalton Trans., 2012,41, 7849-7851
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    Conversion of {Fe(NO)2}10 dinitrosyl iron to nitrato iron(III) species by molecular oxygen

    K. M. Skodje, P. G. Williard and E. Kim, Dalton Trans., 2012, 41, 7849
    DOI: 10.1039/C2DT30443K

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