A two-fold interpenetrating microporous metal–organic framework, MMCF-1, has been constructed via the self-assembly of a custom-designed macrocyclic tetracarboxylate ligand and Cd(II), and it exhibits interesting selective uptake of CO2 over N2.
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Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake
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a
Department of Chemistry, University of South Florida, 4202 East Flower Avenue, Tampa, United States
E-mail: sqma@usf.edu ;
Fax: +1-813-974 3203 ;
Tel: +1-813-974 5217
E-mail: sqma@usf.edu ;
Fax: +1-813-974 3203 ;
Tel: +1-813-974 5217
b
ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 S. Cass Avenue, Argonne, USA
CrystEngComm, 2012,14, 6115-6117
DOI: 10.1039/C2CE25484K
Received 02 Apr 2012, Accepted 25 Apr 2012
First published online 26 Apr 2012
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