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Issue 71, 2012
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‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

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Abstract

A general ‘one-pot’ method for determining relative rates of reaction in complex mixtures has been established using free energy relationships to demonstrate its utility. Competition experiments involving as many as seven species gave relative rate constants that are in good agreement to those obtained from individual kinetic analyses.

Graphical abstract: ‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

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Publication details

The article was received on 07 Jun 2012, accepted on 23 Jul 2012 and first published on 24 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34074G
Citation: Chem. Commun., 2012,48, 8937-8939
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    ‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

    H. M. Yau, A. K. Croft and J. B. Harper, Chem. Commun., 2012, 48, 8937
    DOI: 10.1039/C2CC34074G

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