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Issue 63, 2012
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Controlled synthesis and alkaline earth ion binding of switchable formamidoxime-based crown ether analogs

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Abstract

The partial positive charge of amide protons is used to promote macrocyclization and form crown-ether analogs. Their deprotonation generates very selective pH-switchable alkaline earth ion receptors only in the presence of an appropriate substrate.

Graphical abstract: Controlled synthesis and alkaline earth ion binding of switchable formamidoxime-based crown ether analogs

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Publication details

The article was received on 29 Apr 2012, accepted on 25 May 2012 and first published on 29 Jun 2012


Article type: Communication
DOI: 10.1039/C2CC33090C
Citation: Chem. Commun., 2012,48, 7829-7831
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    Controlled synthesis and alkaline earth ion binding of switchable formamidoxime-based crown ether analogs

    Y. Yan, W. Zhao, G. V. Bhagavathy, A. Faurie, N. J. Mosey and A. Petitjean, Chem. Commun., 2012, 48, 7829
    DOI: 10.1039/C2CC33090C

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