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Issue 7, 2011
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Segregation into domains observed in liquid crystal phases: comparison of experimental and theoretical data

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Abstract

The phase diagram of an amidic surfactant, sodium N-dodecanoylprolinate, was investigated by experimental means such as optical microscopy, multinuclear NMR, and SAXS experiments, and by dissipative particle dynamics and all-atoms molecular dynamics simulations. The organization in domains based on the stereochemical information of the surfactant (E and Z), as well as being observed previously under micellar aggregating conditions, was also observed in the liquid crystal phases. The combination of the different experimental techniques and of the theoretical investigation allowed us to clarify the nature of the domains and some of the involved interactions in their segregation and organization.

Graphical abstract: Segregation into domains observed in liquid crystal phases: comparison of experimental and theoretical data

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Publication details

The article was received on 08 Oct 2010, accepted on 04 Jan 2011 and first published on 15 Feb 2011


Article type: Paper
DOI: 10.1039/C0SM01127D
Citation: Soft Matter, 2011,7, 3392-3403
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    Segregation into domains observed in liquid crystal phases: comparison of experimental and theoretical data

    H. Amenitsch, C. Bombelli, S. Borocci, R. Caminiti, F. Ceccacci, S. Concilio, C. La Mesa, G. Mancini, S. Piotto and M. Rappolt, Soft Matter, 2011, 7, 3392
    DOI: 10.1039/C0SM01127D

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