Jump to main content
Jump to site search

Issue 1, 2011
Previous Article Next Article

Rhodium catalyzed allene amidation: a facile entry into 2-amidoallylcations for unusual [3 + 3] annulation reactions

Author affiliations

Abstract

The interaction of a sulfamate ester derived metallonitrene with an allene generates a versatile intermediate with 2-amidoallylcation like reactivity. In this article we outline reactivity patterns for this novel dipolar species, demonstrating both [3 + 2] reactions with benzaldehyde, and unusual [3 + 3] annulation reactions with a variety of nitrones.

Graphical abstract: Rhodium catalyzed allene amidation: a facile entry into 2-amidoallylcations for unusual [3 + 3] annulation reactions

Back to tab navigation

Supplementary files

Publication details

The article was received on 16 Jul 2010, accepted on 17 Aug 2010 and first published on 16 Sep 2010


Article type: Edge Article
DOI: 10.1039/C0SC00375A
Citation: Chem. Sci., 2011,2, 112-116
  •   Request permissions

    Rhodium catalyzed allene amidation: a facile entry into 2-amidoallylcations for unusual [3 + 3] annulation reactions

    A. H. Stoll and S. B. Blakey, Chem. Sci., 2011, 2, 112
    DOI: 10.1039/C0SC00375A

Search articles by author

Spotlight

Advertisements