Issue 10, 2011
From the journal:

Polymer Chemistry

Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide†

Etienne Girard,ab   Thierry Tassaing,c   Jean-Daniel Marty*b  and  Mathias Destarac*a  

* Corresponding authors

a LHFA, UMR 5069, Université de Toulouse, 118, route de Narbonne, Toulouse, Cedex 9, France
E-mail: destarac@chimie.ups-tlse.fr

b IMRCP, UMR 5623, Université de Toulouse, 118, route de Narbonne, Toulouse, Cedex 9, France
E-mail: marty@chimie.ups-tlse.fr

c ISM, UMR 5255 CNRS- Université Bordeaux 1, 351 cours de la Libération, Talence Cedex, France

Abstract

We investigated the structure–property relationships between poly(vinyl acetate)-based (co)polymers and their solubility in supercritical carbon dioxide. Building on RAFT/MADIX polymerization, key macromolecular characteristics—chain length, chain-end group and composition—of these (co)polymers were studied. Their solubility in sc-CO2 was determined by high-pressure infrared spectroscopy, thereby providing guidelines for their design.

Graphical abstract: Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/C1PY00209K
Article type
Paper
Submitted
12 May 2011
Accepted
15 Jun 2011
First published
20 Jul 2011

Polym. Chem., 2011,2, 2222-2230

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Influence of macromolecular characteristics of RAFT/MADIX poly(vinyl acetate)-based (co)polymers on their solubility in supercritical carbon dioxide

E. Girard, T. Tassaing, J. Marty and M. Destarac, Polym. Chem., 2011, 2, 2222 DOI: 10.1039/C1PY00209K

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