Issue 8, 2011
From the journal:

Organic & Biomolecular Chemistry

Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides†

Christian Bukoveca  and  Uli Kazmaier*a  

* Corresponding authors

a Institut für Organische Chemie, Universität des Saarlandes, Saarbrücken, Germany
E-mail: u.kazmaier@mx.uni-saarland.de
Fax: + 49 681 302 2409
Tel: + 49 681 302 3409

Abstract

Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl]2 as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized buiding blocks in excellent yields.

Graphical abstract: Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides

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Article information

DOI
https://doi.org/10.1039/C0OB00945H
Article type
Paper
Submitted
27 Oct 2010
Accepted
10 Feb 2011
First published
07 Mar 2011

Org. Biomol. Chem., 2011,9, 2743-2750

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Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides

C. Bukovec and U. Kazmaier, Org. Biomol. Chem., 2011, 9, 2743 DOI: 10.1039/C0OB00945H

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