We have fabricated an organic/inorganic hybrid thin film based on a Dawson-type polyoxometalate P2W18O626− (P2W18) and a luminescent transition metal complex tris(2,2′-bipyridine)ruthenium [Ru(bpy)3]2+ (Rubpy) by using a layer-by-layer assembly technique, which functions as an electroswitchable fluorescent device operated by electrochemical stimulation.
B. Wang, L. Bi and L. Wu, J. Mater. Chem., 2011, 21, 69 DOI: 10.1039/C0JM03140B
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