Issue 45, 2011

Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates”

Abstract

The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH3CN give rise to the formation of lanthanide luminescent ‘half-helicates’ in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.

Graphical abstract: Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates”

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2011
Accepted
18 Aug 2011
First published
22 Sep 2011

Dalton Trans., 2011,40, 12056-12059

Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(III) luminescent “half-helicates”

C. Lincheneau, C. Destribats, D. E. Barry, J. A. Kitchen, R. D. Peacock and T. Gunnlaugsson, Dalton Trans., 2011, 40, 12056 DOI: 10.1039/C1DT11225B

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