1,3-Dipolar cycloaddition between a metal–azide (Ph3PAuN3) and a metal–acetylide (Ph3PAuC
CPh): an inorganic version of a click reaction†
Abstract
This report describes the synthesis and characterization of 1,5-bis-triphenylphosphinegold(I) 1,2,3-triazolate (3(1,5)). The synthesis of the dinuclear complex 3(1,5) is achieved via an unprecedented inorganic click (iClick) reaction between the metal–CPh (2). Characterization of 3(1,5) includes multinuclear