Issue 38, 2011
From the journal:

Dalton Transactions

A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate†

Li-Juan Chen,ab   Jiang-Bo Su,a   Rong-Bin Huang,c   Shen Lin,*ab   Ming-Xing Yangab  and  Hua Huanga  

* Corresponding authors

a College of Chemistry and Materials, Fujian Normal University, China
E-mail: shenlin@fjnu.edu.cn
Fax: +0086-591-83465393
Tel: +0086-591-22868191

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian, China

c College of Chemistry and Chemical Engineering, Xiamen University, People's Republic of China

Abstract

A 2D tri-layer compound {[Co8(tbip)6(H2O)9(OH)4]·12(H2O)}n (1) (H2tbip = 5-tert-butyl isophthalic acid) consisting of novel heptacobaltate clusters and single cobalt centers bridged by tbip2− ligands has been hydrothermally synthesized. The complex represents a rare example of a homometallic coordination polymer built up from both heptanuclear metal clusters and single metal centers simultaneously. The magnetic investigation reveals that the complex exhibits the overall predominance of antiferromagnetic coupling between magnetic centers.

Graphical abstract: A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate

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Article information

DOI
https://doi.org/10.1039/C1DT10723B
Article type
Paper
Submitted
20 Apr 2011
Accepted
20 Jul 2011
First published
22 Aug 2011

Dalton Trans., 2011,40, 9731-9736

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A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate

L. Chen, J. Su, R. Huang, S. Lin, M. Yang and H. Huang, Dalton Trans., 2011, 40, 9731 DOI: 10.1039/C1DT10723B

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