Donor-stabilised cations, phosphinamide anions, and unusual oxidative cyclisation products from halogenated phosphoranimines and phosphinimines with a bulky 2,4,6-tri-tert-butylphenyl substituent at nitrogen†
Abstract
New aspects of the chemistry of the phosphoranimine Cl3PNMes* (Mes* = 2,4,6-tri-tert-butylphenyl) (7) and the phosphinimine ClPNMes* (2) have been explored. A cationic derivative of 7 was prepared from the reaction between this species and
- This article is part of the themed collection: Dalton Transactions 40th Anniversary