Issue 45, 2011
From the journal:

Dalton Transactions

Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water†

Simon A. Barrett,a   Colin A. Kilnera  and  Malcolm A. Halcrow*a  

* Corresponding authors

a School of Chemistry, University of Leeds, Woodhouse Lane, Leeds
E-mail: m.a.halcrow@leeds.ac.uk
Fax: +44 113 343 6565
Tel: +44 113 343 6506

Abstract

The temperature of spin-crossover in [Fe(3-bpp)2][BF4]2 (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) tends to increase in associating solvents. In particular, T½ shifts to 60–70 K higher temperature in water compared to organic solvents.

Graphical abstract: Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1DT10620A
Article type
Communication
Submitted
11 Apr 2011
Accepted
06 May 2011
First published
16 May 2011

Dalton Trans., 2011,40, 12021-12024

Permissions

Request permissions

Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents – A dramatic stabilisation of the low-spin state in water

S. A. Barrett, C. A. Kilner and M. A. Halcrow, Dalton Trans., 2011, 40, 12021 DOI: 10.1039/C1DT10620A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements