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Issue 22, 2011
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Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

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Abstract

The ZnMe complexes of bis-ferrocenyl-β-diketiminate ligands are prepared and the reactions with [Ph3C][B(C6F5)4] are found to yield the salts [H(Ph3C)C(MeC(N(C5H4)FeCp)2ZnMe] [B(C6F5)4] and [CH2[double bond, length as m-dash]C(MeC(N(C5H4)FeCp)2ZnMe][B(C6F5)4], derived from electrophilic substitution and hydride abstraction.

Graphical abstract: Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

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Publication details

The article was received on 17 Mar 2011, accepted on 06 Apr 2011 and first published on 05 May 2011


Article type: Communication
DOI: 10.1039/C1DT10452G
Citation: Dalton Trans., 2011,40, 5836-5840
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    Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

    L. J. E. Stanlake and D. W. Stephan, Dalton Trans., 2011, 40, 5836
    DOI: 10.1039/C1DT10452G

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