Assembly of a dinuclear silver complex containing an Ag2S2 motif from a phosphorus-supported trishydrazone ligand. P
S→AgI coordination†
Abstract
The reaction of the phosphorus trihydrazide, (S)P[N(Me)-NH2]3 (1) with CH-2-C9H6N]3 (2). Crystals of 2 were grown in three different
) crystal forms. Each of these, while possessing an essentially similar molecular structure, adopt different crystal packing giving rise to supramolecular structures mediated by a variety of weak interactions: O–H–N, O–H–O, C–H–N, C–H–O, C–H–S, C–H–π, π–π, N–π and S–π. The reaction of 2 with Ag(ClO4)2·6H2O in
CH-2-C9H6N]3}·ClO4]2 (3). The molecular structure of 3 reveals a dimeric structure consisting of two AgI ions that are held together by two
S→AgI coordination is seen. This results in the formation of an Ag2S2 dimer that is encapsulated by two trishydrazone