Bridging, terminal, free, anti and gaucheBPA ligands in a 1D hybrid organic–inorganic MnII-cyanate system

Noelia De la Pinta; Luz Fidalgo; Gotzon Madariaga; Franz A. Mautner; Luis Lezama; Roberto Cortés

doi:10.1039/C1DT10257E

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Bridging, terminal, free, anti and gaucheBPA ligands in a 1D hybrid organic–inorganic Mn^II-cyanate system†

Noelia De la Pinta,^a Luz Fidalgo,^b Gotzon Madariaga,^c Franz A. Mautner,^d Luis Lezama^a and Roberto Cortés*^a

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* Corresponding authors

^a Departamento de Química Inorgánica, Fac. Ciencia y Tecnología, UPV/EHU, Aptdo. 644, Bilbao, Spain
E-mail: roberto.cortes@ehu.es
Fax: +34 94601 3500
Tel: +34 94 601 5150

^b Departamento de Química Inorgánica, Fac. Farmacia, UPV/EHU, Aptdo. 450, Vitoria-Gasteiz, Spain
Fax: +34 94501 3019
Tel: +34 945 01 3089

^c Departamento de Física de la Materia Condensada, Fac. Ciencia y Tecnología, UPV/EHU, Aptdo. 644, Bilbao, Spain
Fax: +34 94601 3500
Tel: +34 94601 5487

^d Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, Rechbauerstraße 12, Graz, Austria
Fax: +43 316 873 8225
Tel: +43 316 873 8234

Abstract

A hybrid organic–inorganic chain compound of the family Mn(II)-bpa-(NCO) is presented. It contains, unusually, five different dispositions for the bpa [1,2-bis(4-pyridyl)ethane] ligand. Water molecules and free bpa ligands occupy the voids of the structure. The compound shows significant antiferromagnetic-type interactions as a consequence of different exchange pathways.

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Article information

DOI: https://doi.org/10.1039/C1DT10257E
Article type: Paper
Submitted: 15 Feb 2011
Accepted: 04 Apr 2011
First published: 03 May 2011

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Dalton Trans., 2011,40, 6033-6037

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Bridging, terminal, free, anti and gaucheBPA ligands in a 1D hybrid organic–inorganic Mn^II-cyanate system

N. De la Pinta, L. Fidalgo, G. Madariaga, F. A. Mautner, L. Lezama and R. Cortés, Dalton Trans., 2011, 40, 6033 DOI: 10.1039/C1DT10257E

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Dalton Transactions