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Issue 20, 2011
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Catalysis of Kumada–Tamao–Corriu coupling by a (POCOP)Rh pincer complex

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Abstract

A pincer-based (POCOP)Rh catalyst is demonstrated to be an active and well-defined catalyst for the coupling of select aryl and alkyl Grignards with aryl iodides. The proposed intermediacy of oxidative addition of aryl halides to (POCOP)RhI is supported by the isolation of the oxidative addition product.

Graphical abstract: Catalysis of Kumada–Tamao–Corriu coupling by a (POCOP)Rh pincer complex

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Publication details

The article was received on 29 Jan 2011, accepted on 22 Feb 2011 and first published on 11 Mar 2011


Article type: Communication
DOI: 10.1039/C1DT10161G
Citation: Dalton Trans., 2011,40, 5426-5429
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    Catalysis of Kumada–Tamao–Corriu coupling by a (POCOP)Rh pincer complex

    S. D. Timpa, C. M. Fafard, D. E. Herbert and O. V. Ozerov, Dalton Trans., 2011, 40, 5426
    DOI: 10.1039/C1DT10161G

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