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Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse wateroxidation which was followed by using Clark electrode and online mass spectrometry.
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