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Issue 12, 2011
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Trigonal propeller-shaped [MnIII3MIINa] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

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Abstract

Two new polynuclear heterometallic cluster complexes with [MnIII3MIINa] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [MnIIICaIINa] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.

Graphical abstract: Trigonal propeller-shaped [MnIII3MIINa] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

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Publication details

The article was received on 25 Oct 2010, accepted on 19 Jan 2011 and first published on 15 Feb 2011


Article type: Communication
DOI: 10.1039/C0DT01463J
Citation: Dalton Trans., 2011,40, 2699-2702
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    Trigonal propeller-shaped [MnIII3MIINa] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII

    S. Nayak, H. P. Nayek, S. Dehnen, A. K. Powell and J. Reedijk, Dalton Trans., 2011, 40, 2699
    DOI: 10.1039/C0DT01463J

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