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Issue 9, 2011
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A recyclable perfluoroalkylated PCP pincer palladium complex

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Abstract

A new fluorous PCP pincer ligand has been coordinated to Ni(II), Pd(II) and Pt(II). The air stable palladium complex, which promotes Heck reactions between methyl acrylate and either aryl bromides or iodides, can be recovered intact by fluorous solid-phase extraction and was reused four times in the Heck reaction between methyl acrylate and 4-bromoacetophenone without loss in catalytic activity.

Graphical abstract: A recyclable perfluoroalkylated PCP pincer palladium complex

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Publication details

The article was received on 12 Aug 2010, accepted on 30 Nov 2010 and first published on 24 Jan 2011


Article type: Paper
DOI: 10.1039/C0DT01004A
Citation: Dalton Trans., 2011,40, 1998-2005
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    A recyclable perfluoroalkylated PCP pincer palladium complex

    D. Duncan, E. G. Hope, K. Singh and A. M. Stuart, Dalton Trans., 2011, 40, 1998
    DOI: 10.1039/C0DT01004A

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