Molecular spectroscopy for ground-state transfer of ultracold RbCs molecules

Abstract

We perform one- and two-photon high resolution spectroscopy on ultracold samples of RbCs Feshbach molecules with the aim to identify a suitable route for efficient ground-state transfer in the quantum-gas regime to produce quantum gases of dipolar RbCs ground-state molecules. One-photon loss spectroscopy allows us to probe deeply bound rovibrational levels of the mixed excited (A¹Σ⁺ − b³Π)0⁺ molecular states. Two-photon dark state spectroscopy connects the initial Feshbach state to the rovibronic ground state. We determine the binding energy of the lowest rovibrational level |v′′ = 0, J′′ = 0〉 of the X¹Σ⁺ ground state to be D^X₀ = 3811.5755(16) cm⁻¹, a 300-fold improvement in accuracy with respect to previous data. We are now in the position to perform stimulated two-photon Raman transfer to the rovibronic ground state.