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Issue 6, 2011
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Surface reaction and transport in mixed conductors with electrochemically-active surfaces: a 2-D numerical study of ceria

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Abstract

A two-dimensional, small-bias model has been developed for describing transport through a mixed ionic and electronic conductor (MIEC) with electrochemically-active surfaces, a system of particular relevance to solid oxide fuel cells. Utilizing the h-adaptive finite-element method, we solve the electrochemical potential and flux for both ionic and electronic species in the MIEC, taking the transport properties of Sm0.15Ce0.85O1.925−δ (SDC15). In addition to the ionic flux that flows between the two sides of the cell, there are two types of electronic fluxes: (1) cross-plane current that flows in the same general direction as the ionic current, and (2) in-plane current that flows between the catalytically-active MIEC surface and the metal current collectors. From an evaluation of these fluxes, the macroscopic interfacial resistance is decomposed into an electrochemical reaction resistance and an electron diffusion-drift resistance, the latter associated with the in-plane electronic current. Analysis of the experimental data for the interfacial resistance for hydrogen electro-oxidation on SDC15 having either Pt or Au current collectors (W. Lai and S. M. Haile, J. Am. Ceram. Soc., 2005, 88, 2979–2997; W. C. Chueh, W. Lai and S. M. Haile, Solid State Ionics, 2008, 179, 1036–1041) indicates that surface reaction rather than electron migration is the overall rate-limiting step, and suggests furthermore that the surface reaction rate, which has not been directly measured in the literature, scales with Image ID:c0cp01219j-t1.gif. The penetration depth for the in-plane electronic current is estimated at 0.6 μm for the experimental conditions of interest to SDC15, and is found to attain a value as high as 4 μm within the broader range of computational conditions.

Graphical abstract: Surface reaction and transport in mixed conductors with electrochemically-active surfaces: a 2-D numerical study of ceria

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Publication details

The article was received on 16 Jul 2010, accepted on 07 Sep 2010 and first published on 30 Nov 2010


Article type: Paper
DOI: 10.1039/C0CP01219J
Citation: Phys. Chem. Chem. Phys., 2011,13, 2121-2135
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    Surface reaction and transport in mixed conductors with electrochemically-active surfaces: a 2-D numerical study of ceria

    F. Ciucci, W. C. Chueh, D. G. Goodwin and S. M. Haile, Phys. Chem. Chem. Phys., 2011, 13, 2121
    DOI: 10.1039/C0CP01219J

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