Issue 23, 2011

An unprecedented twofold interpenetrated layered metal–organic framework with a MoS2-H topology

Abstract

An unprecedented twofold interpenetrated layered metal–organic framework with a two-dimensional 3,6-connected net topology has been prepared using a tricarboxylic acid as a 3-connected node and a Zn4O(COO)6 cluster as a 6-connected node, where the ligand flexibility and the combination of π–π stacking and hydrogen bonding interactions render the 6-connected node into a topological trigonal prismatic node.

Graphical abstract: An unprecedented twofold interpenetrated layered metal–organic framework with a MoS2-H topology

Supplementary files

Article information

Article type
Communication
Submitted
25 Jul 2011
Accepted
22 Sep 2011
First published
10 Oct 2011

CrystEngComm, 2011,13, 6926-6929

An unprecedented twofold interpenetrated layered metal–organic framework with a MoS2-H topology

L. Rajput, S. Hong, X. Liu, M. Oh, D. Kim and M. S. Lah, CrystEngComm, 2011, 13, 6926 DOI: 10.1039/C1CE06038D

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