Issue 10, 2011
From the journal:

CrystEngComm

Chloride templated formation of {Dy12(OH)16}20+ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate†

Yan-Li Miao,ab   Jun-Liang Liu,a   Ji-Dong Leng,a   Zhuo-Jia Lina  and  Ming-Liang Tong*ac  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry/State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, P. R. China
E-mail: tongml@mail.sysu.edu.cn

b College of Science, Guangdong Ocean University, Zhanjiang, P. R. China

c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China

Abstract

Two unique dysprosium(III) coordination compounds with similar dodecanuclear clusters composed of four vertex-sharing cubane-like units, [2Cl− ⊂ {Dy12(OH)16(phenda)8(H2O)8}]2+, were reported. Magnetic studies reveal that both compounds exhibit slow magnetic relaxation.

Graphical abstract: Chloride templated formation of {Dy12(OH)16}20+ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate

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Article information

DOI
https://doi.org/10.1039/C1CE05211J
Article type
Communication
Submitted
17 Feb 2011
Accepted
22 Mar 2011
First published
06 Apr 2011

CrystEngComm, 2011,13, 3345-3348

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Chloride templated formation of {Dy12(OH)16}20+ cluster core incorporating 1,10-phenanthroline-2,9-dicarboxylate

Y. Miao, J. Liu, J. Leng, Z. Lin and M. Tong, CrystEngComm, 2011, 13, 3345 DOI: 10.1039/C1CE05211J

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