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Department of Chemistry, The George Washington University, 725 21st, Street, Washington, DC, USA
E-mail: cahill@gwu.edu
; Fax: +1 (202) 994-5873
; Tel: +1 (202) 994-6959
CrystEngComm, 2011,13, 153-157
DOI:
10.1039/C0CE00231C
Received
25 May 2010,
Accepted
22 Jul 2010
First published online
27 Aug 2010
A two dimensional UO22+ coordination polymer, (UO2)3(C10H5N3O4)2(OH)2(H2O)2, has been synthesized under solvothermal conditions. The triazolate ligand, 1-(4-carboxyphenyl)-1H-1,2,3-triazole-4-carboxylic acid (CPTAZ) has been generated via a 1,3-dipolar cycloaddition of 4-azidobenzoic acid and propiolic acid. Reactions of the UO22+ cation with both the in situ generated triazolate ligand and the presynthesized ligand have been explored. The structure, fluorescent and thermal behaviour of this material are presented, as is a discussion of the utility of in situ ligand formation versus direct assembly.
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