Issue 44, 2011
From the journal:

Chemical Communications

Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide†‡

Ya Du,a   Todd K. Hystera  and  Tomislav Rovis*a  

* Corresponding authors

a Department of Chemistry, Colorado State University, Fort Collins, CO, USA
E-mail: rovis@lamar.colostate.edu
Fax: +1 970 491-1801
Tel: +1 970 491-7208

Abstract

An efficient strategy for the oxidative carbonylation of aromatic amidesvia C–H/N–H activation to form phthalimides using an Rh(III) catalyst has been developed. The reaction shows a preference for C–H bonds of electron-rich aromatic amides and tolerates a variety of functional groups.

Graphical abstract: Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

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Article information

DOI
https://doi.org/10.1039/C1CC15843K
Article type
Communication
Submitted
21 Sep 2011
Accepted
04 Oct 2011
First published
17 Oct 2011

Chem. Commun., 2011,47, 12074-12076

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Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

Y. Du, T. K. Hyster and T. Rovis, Chem. Commun., 2011, 47, 12074 DOI: 10.1039/C1CC15843K

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