Issue 45, 2011

A highly efficient precatalyst for amination of aryl chlorides: synthesis, structure and application of a robust acenaphthoimidazolylidene palladium complex

Abstract

A robust palladium NHC complex was synthesized and exhibits exceptional activity and selectivity as a precatalyst in the amination of aryl chlorides and tolerates a wide range of substrates at low catalyst loadings.

Graphical abstract: A highly efficient precatalyst for amination of aryl chlorides: synthesis, structure and application of a robust acenaphthoimidazolylidene palladium complex

Supplementary files

Article information

Article type
Communication
Submitted
06 Sep 2011
Accepted
10 Oct 2011
First published
19 Oct 2011

Chem. Commun., 2011,47, 12358-12360

A highly efficient precatalyst for amination of aryl chlorides: synthesis, structure and application of a robust acenaphthoimidazolylidene palladium complex

T. Tu, W. Fang and J. Jiang, Chem. Commun., 2011, 47, 12358 DOI: 10.1039/C1CC15503B

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