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Issue 39, 2011
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Coupling of ortho-substituted aryl chlorides with bulky amides

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Abstract

Voluminous amides were coupled with deactivated, sterically hindered aryl chlorides in excellent yields providing products, which have not been efficiently accessible by transition metal catalysis so far. Application of an unsymmetric bisphosphine ligand was critical for the high catalytic activity.

Graphical abstract: Coupling of ortho-substituted aryl chlorides with bulky amides

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Publication details

The article was received on 05 Aug 2011, accepted on 01 Sep 2011 and first published on 12 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14844C
Citation: Chem. Commun., 2011,47, 11095-11097
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    Coupling of ortho-substituted aryl chlorides with bulky amides

    F. C. Falk, R. Fröhlich and J. Paradies, Chem. Commun., 2011, 47, 11095
    DOI: 10.1039/C1CC14844C

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