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Issue 48, 2011
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pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes

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Abstract

Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.

Graphical abstract: pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(i) complexes

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Publication details

The article was received on 03 Aug 2011, accepted on 23 Sep 2011 and first published on 10 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC14799D
Citation: Chem. Commun., 2011,47, 12765-12767
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    pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes

    C. M. Álvarez, R. Carrillo, R. García-Rodríguez and D. Miguel, Chem. Commun., 2011, 47, 12765
    DOI: 10.1039/C1CC14799D

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