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Issue 42, 2011
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Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes

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Abstract

Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl)phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(III), Fe(II), and Mn(II) (3–5). Complexes 3–5 are high-spin and redox active.

Graphical abstract: Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

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Publication details

The article was received on 02 Aug 2011, accepted on 10 Sep 2011 and first published on 26 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14758G
Citation: Chem. Commun., 2011,47, 11680-11682
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    Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes

    G. M. Yee, K. Kowolik, S. Manabe, J. C. Fettinger and L. A. Berben, Chem. Commun., 2011, 47, 11680
    DOI: 10.1039/C1CC14758G

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