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Issue 38, 2011
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Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(II) bis(trimethylsilyl)amide

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Abstract

The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC complexes [(NHC)Fe{N(SiMe3)2}2] (NHC = IPr, 2; NHC = IMes, 3) are reported.

Graphical abstract: Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(ii) bis(trimethylsilyl)amide

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Publication details

The article was received on 26 Jul 2011, accepted on 15 Aug 2011 and first published on 01 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14576B
Citation: Chem. Commun., 2011,47, 10623-10625
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    Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(II) bis(trimethylsilyl)amide

    R. A. Layfield, J. J. W. McDouall, M. Scheer, C. Schwarzmaier and F. Tuna, Chem. Commun., 2011, 47, 10623
    DOI: 10.1039/C1CC14576B

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