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Issue 39, 2011
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Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

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Abstract

Under UV-light irradiation, the anti-Markovnikov hydration of internal arylalkynes proceeds in the cavity of an electron-deficient coordination cage to give benzyl ketones; the reaction is triggered by cage-mediated, photo-induced electron transfer from the alkynes to the cage.

Graphical abstract: Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

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Publication details

The article was received on 25 Jul 2011, accepted on 26 Aug 2011 and first published on 09 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14523A
Citation: Chem. Commun., 2011,47, 10960-10962
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    Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

    T. Murase, H. Takezawa and M. Fujita, Chem. Commun., 2011, 47, 10960
    DOI: 10.1039/C1CC14523A

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