Issue 42, 2011
From the journal:

Chemical Communications

Photoreactive gold(i) macrocycles with diphosphine and trans,trans-muconate ligands†

Mohammad Hedayetullah Mir,‡a   Jun Xiang Ong,a   Goutam Kumar Kole,a   Geok Kheng Tan,a   Michael J. McGlinchey,*b   Yuyang Wu*c  and  Jagadese J. Vittal*ad  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
E-mail: chmjjv@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 2975

b School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland
E-mail: michael.mcglinchey@ucd.ie
Tel: +353 01 716 2880

c Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: y-wu1@northwestern.edu
Tel: +1 847 491 7080

d Department of Chemistry, Gyeongsang National University, Jinju 660-701, S. Korea

Abstract

A pair of trans,trans-muconate ligands have been successfully aligned in two novel Au(I) macrocycles by design from phosphino metal precursors that undergo photochemical cycloaddition reactions quantitatively, resulting in the formation of cyclooctadiene derivatives.

Graphical abstract: Photoreactive gold(i) macrocycles with diphosphine and trans,trans-muconate ligands

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Article information

DOI
https://doi.org/10.1039/C1CC14442A
Article type
Communication
Submitted
21 Jul 2011
Accepted
14 Sep 2011
First published
26 Sep 2011

Chem. Commun., 2011,47, 11633-11635

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Photoreactive gold(I) macrocycles with diphosphine and trans,trans-muconate ligands

M. H. Mir, J. X. Ong, G. K. Kole, G. K. Tan, M. J. McGlinchey, Y. Wu and J. J. Vittal, Chem. Commun., 2011, 47, 11633 DOI: 10.1039/C1CC14442A

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